Fuels of the Future

Environmental Fate and Transport Issues with Alternative Fuels


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Section I: Cross Media

  • Malcolm Pirnie, Inc. (1998). Evaluation of the Fate and Transport of Ethanol in the Environment. Prepared for the American Methanol Institute. Available at: Evaluation of the Fate and Transport of Ethanol Report.

  • This presentation developed by the Malcolm Pirnie company for the Environmental Protection Agency describes the properties, fate and transport, studies, remediation and treatment techniques and research needs for the fate and transport of ethanol. Reference: Kavanaugh, M. and A. Stocking (May 24, 1999). Fate and Transport of Ethanol in the Environment. Available in hard copy library.

  • This presentation provides an overview of properties of alternative oxygenates. Reference: May 11, 2000. Drogos, D. MTBE v. Other Oxygenates. Presented at Mealey's MTBE Conference. Available in hard copy library.



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Section II: Surface Water




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Section III: Ground Water

  • LLNL presentation to the State Water Resources Control Board on "The Life Cycle and Environmental Studies of Ethanol and Alkylates Used in Reformulated Gasoline". This presentation provides preliminary results from the study of Alkylate transport at gasoline sites. Available in the ERD hard copy library.

  • This report prepared by the Institute for Groundwater Research for the California MTBE Research Partnership describes a numerical modeling study undertaken to anticipate the potential groundwater impacts that may result from blending ethanol in gasoline. Reference: Modeling the Impact of Ethanol on the Persistence of BTEX Compounds in Gasoline-contaminated Groundwater (April 2000). Will soon be available at: Modeling the Impact of Ethanol.

  • This report chapter describes the environmental transport and fate of fuel hydrocarbon alkylates in surface and groundwater. Available at: Chapter 6: Environmental Transport and Fate of Fuel Hydrocarbon Alkylates.

  • This article within the Leaking Underground Storage Tanks Bulletin describes various knowledge gaps regarding ethanol and its impact on groundwater. Reference: B. Brannan (1999). With the Possible Phase Out of MTBE, What Do We Know About Ethanol? L.U. S.T.Line, Bulletin 32, pg. 19. Available in ERD hard copy library.

  • This article submitted to the CRC Critical Reviews in Environmental Science and Engineering (2000) provides a comprehensive review of the transport of Ethanol and monoaromatic hydrocarbons (BTEX) in the groundwater system after a gasohol spill. Reference: Powers, S.E., C.S. Hunt, S.E. Heermann, H.X. Corseuil, D. Rice, and P.J.J. Alvarez (2000). The Transport and Fate of Ethanol and BTEX in Groundwater Contaminated by Gasohol. Submitted to CRC Critical Reviews in Environmental Science and Engineering. Available in ERD hard copy library.

  • This paper describes an extensive field experiment that investigated the fate of methanol and MTBE in groundwater as well as their influence on BTEX degradation. Reference: Schirmer, M., J.W. Molson, and J.F. Barker. The Potential Impact of Alcohol as a Gasoline Oxygenate on BTEX Degradation at Spill Sites. Proceedings of the 1999 Petroleum Hydrocarbons and Organic Chemicals in Groundwater Conference, November 17-19, Houston, Ground Water Publishing Company, Westerville, Ohio, pp. 221-228. Available in ERD hard copy library.

  • This report "The Fate and Transport of Ethanol- blended Gasoline in the Environment: A Literature Review and Transport Modeling" (1999) evaluates the fate and transport of ethanol in the environment, specifically in soil and groundwater. Available at: Fate Report.

  • This Final Report (2000) on Reformulated Gasoline describes the transport and clean-up of spills to the subsurface. The report describes the results of a study performed to assess the degree to which the presence of ethanol in gasoline can enhance the subsurface migration of other gasoline compounds, especially the BTEX (benzene, toluene, ethylbenzene, and xylenes) series of aromatic compounds. The report lists many additional reference materials.

  • This paper "Replacing MTBE with Ethanol as a Gasoline Oxygenate - How May Ground Water Resources Be Impacted? (Powers et al 2000)" summarizes some of the critical enviromental fate and transport issues identified in an extensive literature review carried out for the State of Caifornia in anticipation of the phase out of MTBE and its potential replacement with Ethanol. Available in the ERD hard copy library.




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SectionIV: Atmosphere




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Section V: Soil




For more information please contact:

David Rice, Project Manager
Environmental Restoration Division
Lawrence Livermore National Laboratory
P.O. Box 808, L-528
Livermore, California 94551
rice4@llnl.gov (925) 423-5059

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